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Product Details
|
General Description |
Crystalline solid. |
|
Air & Water Reactions |
Hygroscopic . |
|
Reactivity Profile |
LDAO is less basic than the tertiary amine from which LDAO is derived, but still reacts with strong acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. |
|
Fire Hazard |
Flash point data for LDAO are not available. LDAO is probably nonflammable. |
|
Flammability and Explosibility |
Notclassified |
|
Biochem/physiol Actions |
LDAO can be used to disrupt phospholipid bilayer of cells. |
|
Purification Methods |
Crystallise the oxide from acetone or ethyl acetate. [Bunton et al. J Org Chem 52 3832 1987, Beilstein 4 III 410, 4 IV 798.] |
InChI:InChI=1/C14H30NO/c1-3-5-6-7-8-9-10-11-12-13-14-15(16)4-2/h3-14H2,1-2H3/q-1
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N,N-dimethylaminododecane
lauric acid
formic acid
dodecyl-N,N-dimethylamine N-oxide
| Conditions | Yield |
|---|---|
|
With
oxygen;
ruthenium trichloride;
In
water; acetone;
at 100 ℃;
for 16h;
|
2.2 mmol 1.2 mmol 1.8 mmol |
N,N-dimethylaminododecane
dodecyl-N,N-dimethylamine N-oxide
| Conditions | Yield |
|---|---|
|
With
dihydrogen peroxide;
In
water;
at 100 ℃;
for 6h;
|
99.4% |
|
With
2,2,2-Trifluoroacetophenone; dihydrogen peroxide; acetonitrile;
In
tert-butyl alcohol;
at 20 ℃;
for 18h;
chemoselective reaction;
Green chemistry;
|
97% |
|
With
dihydrogen peroxide;
In
methanol;
at 70 ℃;
for 16h;
|
96% |
|
With
dihydrogen peroxide;
In
ethanol;
at 50 ℃;
for 24h;
|
96% |
|
With
oxygen;
In
methanol; water;
at 100 ℃;
for 64h;
under 10500.8 Torr;
Mechanism;
Thermodynamic data;
E(a), ΔS(excit.); other tertiary amines, var. pressure of oxygen and reaction temp.;
|
95% |
|
With
oxygen;
In
methanol; water;
at 100 ℃;
for 64h;
under 10500.8 Torr;
|
95% |
|
With
1,3-dimethyl-5-ethyl-5,10-dihydroalloxazine; dihydrogen peroxide;
In
methanol; water;
for 8h;
Ambient temperature;
|
85% |
|
With
dihydrogen peroxide;
In
methanol; water;
|
81% |
|
With
oxygen;
In
ethanol; water;
at 80 - 115 ℃;
under 51004.1 Torr;
Thermodynamic data;
activation energy;
|
|
|
With
dihydrogen peroxide;
In
isopropyl alcohol;
at 75 ℃;
Kinetics;
Mechanism;
other cyclic amines; var. temp., var. solvent;
|
|
|
With
dihydrogen peroxide;
In
d(4)-methanol; water;
Product distribution;
time dependence; rate enhancement in the presence of 1,3-dimethyl-5-ethyl-5,10-dihydroalloxazine; effect of amount of reagent;
|
|
|
With
ethanol; dihydrogen peroxide;
at 60 ℃;
|
|
|
With
dihydrogen peroxide;
|
|
|
With
methanol; dihydrogen peroxide;
|
|
|
With
tert.-butylhydroperoxide;
vanadia;
In
benzene;
|
|
|
With
dihydrogen peroxide;
at 0 ℃;
for 2h;
|
|
|
With
dihydrogen peroxide;
|
|
|
With
water;
In
ethanol; water;
at 75 ℃;
for 3h;
|
|
|
With
dihydrogen peroxide;
In
isopropyl alcohol;
at 75 ℃;
|
|
|
With
dihydrogen peroxide;
In
water;
|
|
|
With
dihydrogen peroxide;
In
water;
|
|
|
With
dihydrogen peroxide;
In
water;
at 90 ℃;
for 9h;
Purification / work up;
|
|
|
With
water; dihydrogen peroxide;
at 90 ℃;
for 9h;
Product distribution / selectivity;
|
|
|
With
dihydrogen peroxide;
In
ethanol;
at 65 - 70 ℃;
for 6h;
|
N,N-dimethylaminododecane
N,N-dimethylaminododecane
1-dodecene
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